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Homebrew a poison, call it Calistrian Toxin, that causes arousal on a failed saving throw, and you could even throw in some mechanical debuffs like the inability to concentrate on tasks, as the barbarian Rage class feature.
As far as I know there isn't anything that explicitly states that the character gets aroused. Homebrew is probably the way to go on that route.
Check out recreational drugs of golarion, while not explicitly aphrodisiacs, harlot sweets and batchelor snuff may carry the reputation.
Spells:
Unnatural Lust (but the duration is too short to be what you are looking for, even with Extend Spell)
Reckless Infatuation (lasts a LONG time, and could be made into a Potion)
Substances:
Philter of Love (expensive, and requires a high level caster to make, but permanent; unfortunately gives you less control over the victim than the Potion of Reckless Infutuation, but is harder to get rid of)
Pheromones, though Paizo has a strange idea of the effects of arousal... ;-)
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^Pheromones has self-contradictory text: "Alchemical pheromones are clear, odorless liquids . . . They combine the natural scent".