
Fuzzy-Wuzzy |

Um, why would you go through your adopted ancestry if you're human to start with? Humans can take Natural Ambition in any ancestry feat slot.
So let's say you're an elf instead. You can take the general feat Adopted Ancestry: Human and then get Natural Ambition in any remaining ancestry feat slot.
Or you could take Adopted Ancestry: Halfing, then because of that you can take Cultural Adaptability: Human in any 5+ ancestry slot. That gets you a free 1st-level human feat, so you could take Natural Ambition there. And since you are now elf, halfling, and human as far as your ancestry feats are concerned, you can also take Natural Ambition in any remaining ancestry slots.
Hope something in there answers your question.
EDIT: Not actually positive the last (elf-halfing-human) example works. Can Cultural Adaptability give you Adopted Ancestry if you already have Adopted Ancestry from a general feat? Maybe not.

Fuzzy-Wuzzy |

So you're starting as a human with the Versatile heritage, using the general feat that gives you to take Adopted Ancestry (halfling), then using your regular 1st-level ancestry slot to take Halfling Luck. That all works fine. But at level 5 why grab Cultural Adaptability as an adoptive halfling to get Natural Ambition instead of just taking Natural Ambition directly as an actual human?