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Not in this edition, although in Paizo's run of Dragon and Dungeon, there were Improved and Greater Combat Reflexes feats. I believe they were in the githyanki Incursion issues, but my memory could be faulty - it's been a while.
In Pathfinder, you'll need a fortuitous weapon. Check it out!

chaoseffect |

Hey all.
I seem to remember that there is a feat to get 2 AO when someone provokes?
Am I insane?
It's not a feat but you can also get a similar effect in Pathfinder with the Fortuitous weapon property. It is a +1 enchant and 1/round if you hit with an attack of opportunity you can immediately make another attack at -5.

Scott Wilhelm |
With Snake Fang, if your Attack of Opportunity hits, you may make another Attack as an Immediate Action.
Greater Trip Stacks with Vicious Stomp. With Greater Trip, you get an Attack of Opportunity when you Trip your opponent. With Vicious Stomp, you get an Attack of Opportunity when your opponent goes prone.
There is a 3.5 feat, 2-Weapon attack of opportunity, which let you attack with both your weapons given the opportunity, but the 2 weapon penalties apply, and it counts as 2 AoOs toward your Combat Reflexes limit.
There are other tricks I can think of that will let you do something like what you are talking about, but aren't exactly it.