avr |
Emulate a Class Feature wrote:
Sometimes you need to use a class feature to activate a magic item. ... This skill does not let you actually use the class feature of another class. It just lets you activate items as if you had that class feature.
I think when you use a ring of spell knowledge you're actually using a class feature, not just activating an item. So no IMO.
Unfortunately there's no direct equivalent. A shard of psychic power is the equivalent of a page of spell knowledge though, and it'd be a reasonable house rule to let a psychic spellcaster use a ring of spell knowledge.