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This should be in the Rules forum.
As to answer the question, the feat says "You can aim a thrown weapon so it strikes two foes." Combining that with obvious RAI that the targets should be different, I'd say no rational GM would allow it.
Note that Startoss Shower explicitly disallows attacking the same target multiple times.
You can aim a thrown weapon so it strikes two foes.
Prerequisite(s): Dex 13, Point-Blank Shot, Startoss Style, Weapon Focus with the chosen weapon.
Benefit(s): As a standard action, you can make a single ranged thrown weapon attack at your full attack bonus with the chosen weapon. If you hit, you deal damage normally and can make a second attack (at your full attack bonus) against a target within one range increment of the first. You determine cover for this attack from the first target’s space instead of your space.
You can make only one additional attack per round with this feat. If you have Vital Strike, Improved Vital Strike, or Greater Vital Strike, you can add the additional damage from those feats to the initial ranged attack (but not the second attack).
You can strike multiple opponents with thrown weapons.
Prerequisite(s): Dex 13, Point-Blank Shot, Startoss Comet, Startoss Style, Weapon Focus with the chosen weapon, base attack bonus +4.
Benefit(s): When you hit an opponent while using the Startoss Comet feat, you can continue to make attacks against foes that are within one range increment of all previous opponents. You determine cover for each attack from the most recently hit foe’s space instead of your space, and you cannot attack an individual foe more than once during this attack action.
You can make a maximum number of attacks equal to 1 + 1 per 5 points of base attack bonus you possess. If you have Vital Strike, Improved Vital Strike, or Greater Vital Strike, you can add the additional damage from those feats to the initial ranged attack (but not any subsequent attacks).