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Rapid Reload (Combat)
Choose a type of crossbow (hand, light, heavy) or a single type of one-handed or two-handed firearm that you are proficient with. You can reload such a weapon quickly.
Prerequisites: Weapon Proficiency (crossbow type chosen) or Exotic Weapon Proficiency (firearm).
Benefit: The time required for you to reload your chosen type of weapon is reduced to a free action (for a hand or light crossbow), a move action (for heavy crossbow or one-handed firearm), or a standard action (two-handed firearm). Reloading a crossbow or firearm still provokes attacks of opportunity.
Crossbow Mastery (Combat)
Prerequisites: Dex 15, Point-Blank Shot, Rapid Reload, Rapid Shot.
Benefit: The time required for you to reload any type of crossbow is reduced to a free action, regardless of the type of crossbow used. You can fire a crossbow as many times in a full attack action as you could attack if you were using a bow. Reloading a crossbow for the type of crossbow you chose when you took Rapid Reload no longer provokes attacks of opportunity.
Here's my question:
Would Rapid Reload (pistol) qualify as the prerequisite for Crossbow Mastery?AFAICT, it would, but reloading your crossbow would still provoke attacks of opportunity.

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Actually, I'm looking at the Bolt Ace archetype. The crossbow would be the main weapon (able to reload it as a free action with Crossbow Mastery) and the pistol would be the backup weapon (able to reload it as a free action using Rapid Reload and alchemical cartridges). And as long as I retain 1 grit point, reloading the crossbow does not provoke attacks of opportunity.

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<insert obligatory quip about the Bolt Ace being a messy jumble of mismatched class features that results in the inability to use Deadly Aim with Crossbows>
It is, isn't it? ;-)
But regarding Deadly Aim, did you mean "ineffectiveness with" or is the Bolt Ace truly unable to use it with crossbows?

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I think Nefreet is referring to Bolt Ace's first grit ability Sharp Shoot, which allows you to make a touch attack with a crossbow. However, Deadly Aim does not work for touch attacks, with a specific exclusion for firearms, but not crossbows. You can still use deadly aim, just not with Sharp Shoot. So: "ineffectiveness with", yes.