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For the purpose of this question, you have character who is a Monk 6/Rogue 3.
If said character has Snatch Arrows, Deflect Arrows, and Throw Anything; When an NPC fires a bolt from a crossbow from 15' away, (and the monk is aware of said attack), he "snatches the arrow" and throws it back, now the question is, can he apply his sneak attack damage when he throws the crossbow bolt back at that NPC, IF in the intervening time between the moment of the capture of said bolt, and the throwing of it back, said NPC becomes flatfooted, immobilized, or otherwise loses his dexterity?
In my group, we long ago, said, yes, you can. By raw, I can't find anything saying otherwise, nor can I find any references to the same question on the boards here.
tl;dr
npc archer fires bolt, becomes distracted or otherwise engaged in such a way he loses his dex becoming flatfooted, can the monk catching the bolt hit him with it, and his 2d6 of sneak damage?