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![Succubus](http://cdn.paizo.com/image/avatar/A7_Demon-Battle2.jpg)
good template use- pretty good writing (though putting terms in quotes like "adjunct professor" can be confusing/off-putting- was he actually some kind of professor or not, what are you trying to say? are there professors in those guilds?)
taken as a whole, this looks like its reasonably well balanced against a base magus but i'm worried about potential abuse, especially at lower levels. poisons are potent, that's why they're so expensive, and they're normally tempered by low save DCs. at first level a magus could easily have 15 DC on bloodrot, which is normally a 12... nevermind that he doesn't have to pay for it so he can stack applications for higher DC. this could become a must take dip for many classes if they want to use poison- 1 level gets several free poisons/day with same or better DC, and no chance of poisoning themselves.
Another consideration is that poisons, once applied to a weapon, are consumed after the first success hit. This archetype creates "durable" poisons that persist after several hits, which makes the poison use even more powerful and unbalancing, in my opinion.