| Dasrak |
If you're playing a home game, then chained Rogue Talents are subject to GM discretion and you can simply ask if you can take the ki pool talent. If your GM says no, I doubt he'll be receptive to the technical workaround you're proposing. Another option for a home game is the Eldritch Scoundrel archetype, which gains spellcasting and the ability to spontaneously convert spell slots into ki.
I don't believe any of these options work in PFS. The official ruling is that Eldritch Scoundrel is incompatible with the Unchained Rogue (no reason given; I don't see any basis for this in the rules) and the Unchained Rogue is not allowed to pick talents from the Chained Rogue list, period.