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Base classes - can be favored. Prestige classes - unfavorable.
Question is: can an NPC class be treated as favored?
It only says that a prestige class can never be a favored class. There's nothing that says one has to pick a core class, so I don't see why not. Besides, unless you're a PC playing a NPC class, the GM can do whatever (s)he wants.
any non-prestige class, fighter, warrior, wizard, expert all allowed Duelist, Mystic thurge, and racial hitdice are never allowed
A base class is any class that runs from 1 - 20. Ergo, npc classes can have favored class benefits.
Similar question, since it's come up a few times for me - do NPCs benefit from favored class bonuses?
Midnight: yes. Mahor: yes.