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Elemental Ammunition lists its ammunition type as "any", so it's not firearms specific. It definitely works with arrows and although I've never seen anyone do it, I don't see a reason why it wouldn't work with slings.
Compare to something like an Eroding Bullet, where the ammunition type is "round" (which means firearms only).
Magical sling ammunition is of the "sling bullet" type, judging by the Big Rock Bullet!
Yeah, "sling bullet" is the ammunition type for slings. Dispersing bolt also uses that.
Meanwhile Black Powder's ammunition type is "round", and that says it's explicitly used in firearms.
