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Arazni is a deity described in Lost Omens Gods & Magic (page 54). She is neutral evil but allows for chaotic good followers. Would a champion (Liberator) of Arazni be PFS legal?
The Core Rulebook (page 106) states that the champion's deities should be chosen from pages 437 through 440 of the Core Rulebook. I do not know if this has been expanded upon to allow champions to select deities from Gods & Magic. I know that players can worship these deities but I do not know if they allow for champions.
Thanks for sharing your knowledge.

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When you create a character, you can choose their religion or philosophy. If your character is of a class that directly interacts with the divine, such as a cleric or a champion, you must make this choice at first level as part of gaining your class abilities. However, characters of any class might be allowed to certain character options based on the deity they follow. For instance, all followers of Abadar gain access to Abadar’s flawless scale, a magic item considered holy by the faith.
Characters can worship and gain mechanical benefits from any deity listed in the table of gods on page 437 of the Core Rulebook or detailed in Lost Omens Gods & Magic, so long as their alignment matches one of the deity’s listed follower alignments. Note that some deities, such as Rovagug or Urgathoa, allow only evil followers; as Society characters cannot be lawful evil, neutral evil, or chaotic evil, these deities cannot be worshiped to gain benefits in Society play. Characters can also be agnostic, atheist, or can follow the tenets of philosophies (Lost Omens Gods & Magic 94–101) rather than deities.
According to the Character Options Blog from January (as amended periodically), that seems legal to me. I would just say, that as a Chaotic Good follower of an otherwise evil god, you're still bound by the Society restrictions on evil actions and the unwritten rule of "don't be THAT guy".