* Construct Armour - wear any Construct your Size as Breastplate Armour. To make it magical just add an Armour Modification to grant the Construct a Magic Armour Property, (e.g., Deathless, Fortification, Spell Storing, one of the Energy Resistances; etc.).
* Construct Limb - wear any Small/Tiny Construct as an arm covering that provides the Benefits/Penalties of an Heavy Steel Shield, (which you are considered Proficient with). You can also utilize the Construct's Special Attacks, using its modifiers but treating you as the source.
* Jellyfish, Bathysphere - can be worn over the head of a Small/Medium Creature to provide breathable air underwater.
* Oni, Spirit Oni - can be worn as a mask to provide a +2 Insight Bonus to Perception checks.
You can wear anything with engulf if you don't mind dying.
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A Cloaker can be worn as a cloak that... eats you?
Although, now I'm thinking that taxidermied cloaker is a fashion statement.
They're intelligent, non-evil, (not immune to mind-affecting,) and their description states that "stories linger of cloakers that ally with other creatures, hitching a ride on their backs and aiding in their ally’s protection for their own inscrutable reasons."
They can use their Moan ability to help their "wearer", they just have to use their Moan abilities outside of fights until the wearer succeeds at the saving throw and becomes immune for 24 hours.
Also, Raktavarna Rakshasa can "take the shape of a handheld object, most often an ornamental light, a one-handed weapon, or a piece of treasure."
Not exactly worn, but "wielded" is pretty similar.
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