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Faster Than Light has a couple of good tunes that've worked well for me so far.
I like how that game's OST has alternate layered versions of each song for exploration and combat scenes. If I could ever figure out how to pull off that trick in a music player, I'd consider using it in a homegame.
Edit: While the overall OST doesn't match the genre, My Hero Academia has a few great tracks that are hype enough to fit in a whole bunch of things, Starfinder included.

Ithnaar |

For slow, inobtrusive background atmospherics, I'm a fan of Brian Eno, especially the music he did on the "Apollo" soundtrack (for a feature length documentary about the space program).
For a more orchestral sound, I've used the CD soundtrack from the LucasArts game "The Dig" in more than one RPG. Good mix of slow and fast paced tracks.

Azih |

I know it's a bump but I was trawling around youtube for music to set scenes for Dead Sounds Book One and I had a lot of success with:
New Shadowrun games soundtrack
Deus Ex games
Invisible Inc soundtrack.
Mirror's Edge soundtrack.
Voltron Legendary Defenders Soundtrack
Some of these are mentioned already. But there's also this dude:
https://www.youtube.com/channel/UCdEEFrPBkT5WLeRCl2qsEJQ
Seems to spit out movie quality soundtracks on an hourly basis. At least that's what it feels like. And all usefully titled too! Suspensful music! Chase Music! Sad Music!

JetSetRadio |
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I believe music really helps set the mode and gets players invested in a particular scene. Soundtracks I continuous refer back to for sci-fi settings like Shadowrun/Starfinder are songs made by the band Infected Mushroom.
Songs like: Cities of the future, Becoming Insane, Bust a move, Saeed, Psycho and really the list goes on. They start slow but the build up conveys tension.
Side Note: Want some really Good bar/club scenes music use Parov Stelar. Songs like Booty Swing, Catgroove, and Clap Your Hands. These are electro swing songs and every time I put it on someone asks what it is. Then they say it reminds them of any bar scene in the StarWars movies.

Krathanos |

Nixitur |

Seconding (thirding?) that FTL: Faster Than Light has a fantastic soundtrack.
Check this out for an exploration theme.

WhiteWeasel |

For ambient/enviromental music, I like the stellaris soundtrack. Here a few of my favorites.
-Synthetic God Triune theme anyone?
-Dragon Breath A great theme for an advanced city/station that is ahead of the technological average.
-Battle for Supremacy The perfect kind of track for an inciting incident.
For general combat music, I love using the XCOM 2 Soundtrack.
-Combat 1 Tense, heroic and bombastic.
-ADVENT Combat 2 Tense and dire, like a grueling battle.
Also, since the FTL soundtrack is cited here, you guys know the composer Ben Prunty has a whole repertoire to pick from beyond FTL?
-Too Class Tense and dramatic to convey a sense of building urgency and direness.
-Dark Flow Battle Ethereal and advanced, great for high level mystics and technomancers.
-Color Sky It's hard to describe. It's like a building sense of urgency that quiets down and exploded into upbeat and triumph.
I also have many others that come to mind, but I spammed enough links as it is.