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You can throw 2-handed weapons.
It just takes a full-round action to throw it once.
From the PRD wrote:
Thrown Weapons: Daggers, clubs, shortspears, spears, darts, javelins, throwing axes, light hammers, tridents, shuriken, and nets are thrown weapons. The wielder applies his Strength modifier to damage dealt by thrown weapons (except for splash weapons). It is possible to throw a weapon that isn't designed to be thrown (that is, a melee weapon that doesn't have a numeric entry in the Range column on Table: Weapons), and a character who does so takes a –4 penalty on the attack roll. Throwing a light or one-handed weapon is a standard action, while throwing a two-handed weapon is a full-round action. Regardless of the type of weapon, such an attack scores a threat only on a natural roll of 20 and deals double damage on a critical hit. Such a weapon has a range increment of 10 feet.
Bold on the relevant point.
Since you are wielding the weapon in both hands, I would say Startoss would not apply. A trident will do the same base damage dice, but has a smaller range increment (10 vs 20) and is a martial weapon vs simple.If you were set on spear, perhaps a spear sized for a small creature (assuming you were medium sized) this should bring it down to a 1h weapon. It would keep the x3 crit multiplier and the brace quality, but otherwise it would be the same as a Shortspear... at a -2 to hit.
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Alexander Augunas wrote:
First, the weapon needs to be in the thrown fighter weapon group. Simply being "throwable" isn't enough, even if the weapon has a range increment.
Second, you can only use the style when wielding a weapon in one hand, and using nothing in your off-hand.
My answer would be "No."
1) Spear is in the thrown weapon fighter group.
2) A Small Spear as I noted would be a 1-handed weapon anyway.