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If a rogue is using offensive defense and hits multiple times in the same round, does the bonus to ac "armour class" stack with itself?
No See your question about stacking bonus's
FAQ answers this: http://paizo.com/paizo/faq/v5748nruor1fn#v5748eaic9p1m
While the FAQ isn't decisive, I think that it does contain the exact words that anyone needs to use this Talent "correctly": 'While we haven’t reached a final decision on what to do about this talent, we are leaning toward this solution: the dodge bonus only applies against the creature you sneak attacked, and the dodge bonus does not stack with itself. This prevents you from getting a dodge bonus to AC against a strong creature by sneak attacking a weak creature, and prevents you from reaching an absurdly high AC by sneak attacking multiple times in the same round.'