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I doubt this will work, but I wanted to check here, If I have a merciful weapon, do I get to add the bonus 1d6 when sundering?
Only if the merciful quality is "turned off." The weapon then does lethal damage but doesn't get the bonus +1d6. When merciful is "on," the weapon can't hurt objects (or creatures immune to nonlethal damage) at all.
So no pinatas.
Would be great if it worked. Gonna subdue the heck outta that door!