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So I know that any character can join any faction, but certain ones seem to be associated with particular alignments. For instance, Silver Crusade is obviously LG, Andoran is CG, Cheliax is LE, even though characters can't be evil.
So is there a list of all of them with alignments somewhere? I'm thinking of making a Scarzni character, just because there aren't any in my local group, and I was trying to figure out what their alignment would be. Is the organized crime actually organized enough to be lawfully aligned?

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I think in the old guide they all had an alignment next to their description...
Found my old guide (3.0.3) and for the original five -
Andoran - NG
Cheliax - LE
Osirion - LN
Qadira - TN
Taldor - TN
Unfortunately, there doesn't seem to be anything like that for the newer five. I'd class Sczarni as LN personally, but I don't know much about them.

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There's half of what you're looking for in the Pathfinder Field Guide. Listed with each faction (end of the "whatever faction pathfinder" section) there is mention of what they generally are. This isn't what that group is per-say, but it is what most of their pathfinders are.
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..
Grand Lodge - Neutral Aligned
Lantern Lodge - Neutral Aligned
Sczarni - Chaotic Aligned
Shadow Lodge - Chaotic Aligned
Silver Crusade - Good Aligned