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Could you use the pigments to paint a door/window on a wall to allow passage?
I found this on the wizards site.
Nolzur's marvelous pigments is an example of a magic item that benefits those few PCs that take ranks in a skill that doesn't get much use by most adventurers -- specifically Craft (painting). On those rare occasions when such an item shows up in a random treasure roll that can benefit a character, run with it and hopefully the player will do the same. Here are some hooks that might spur you to use Nolzur's marvelous pigments in your campaign:
* A thief with an eye for shape and color uses Nolzur's marvelous pigments to create doors, windows, ladders, and other ways to bypass the walls and gates of a bank, armory, or lord's manor. Because the items created are nonmagical in nature, they do not trigger any of the location's defenses that activate when sensing magic intrusions."
