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Can reach spell be used with scrolls?
Yes, it just requires that you cast a spell. It doesn't specify how.
So - also with wands, staves, and spellhearts then. *makes mental note*
Correct. Unless it says it has to come from a slot, it doesn't. If you want to i.e. cast contingency with the inner spell being containment from a wand, you can, nothing prohibits it.
Anything that uses the Cast a Spell activity, which does mean that certain activatable items does not qualify, but yeah all of those do qualify.
Demon mask is a thing that comes to mind as you Interact with it to have it cast the spell for you.