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Euphoric Cloud, when casted, the creature in the cloud will takes a Fort. save. If it passes, when comes to its round, at the beginning of the round it will takes another save.
I'm not sure if I get it right.
Spoiler:
Euphoric Cloud
Source Advanced Class Guide pg. 181, Dark Markets - A Guide to Katapesh pg. 57
School conjuration (creation) [poison]; Level arcanist 2, druid 2, hunter 2, magus 2, mesmerist 2, psychic 2, sahirafiyun 2, sorcerer 2, witch 2, wizard 2
Casting
Casting Time 1 standard action
Components V, S, M (rare mushrooms worth 5 gp)
Effect
Range medium (100 ft. + 10 ft./level)
Effect fog spreads in 20-ft. radius, 20 ft. high
Duration 1 round/level
Saving Throw Fortitude negates (see text); Spell Resistance no
Description
You create a bank of fog similar to that created by fog cloud except its vapors are intoxicating. Living creatures in the cloud become fascinated. This condition lasts as long as a creature is in the cloud and for 1d4+1 rounds after it leaves. Any creature that succeeds at its save but remains in the cloud must continue to save each round on your turn.
They save on your turn in the initiative order against this spell, not on their own. They get their own actions when their turn comes around before you get to act again so just one save, assuming they leave then.