| Dragonchess Player |
Adventure Path Charter Subscriber; Pathfinder Rulebook, Starfinder Adventure Path, Starfinder Roleplaying Game, Starfinder Society Subscriber
The only NPC that has a chance of "outshining" the PCs is Arueshalae, but the restrictions on her actions as she seeks redemption tend to limit her impact. She is definitely more powerful than a PC when they meet her and possibly gain her help toward the end of the third adventure; after that, she is basically "off-screen" for the most part until the PCs hit 15th level/7th tier.
She is still probably a better archer than most PCs, unless that is their dedicated focus.
The other NPCs shouldn't gain mythic tiers. At most, if they will be accompanying the PCs on a regular basis, then give them the Mythic Companion feat; they are meant to be allies and (possibly) cohorts, not GMPCs.