Vouchsafing a Viable View to Vivify the Valiant Visage of the Vanquishing Vagabond of Vengeance via Variant Valence Vocations - or, simply, "How to Build V with Variant Multiclassing"

[chbgraphicarts]

Scout Swashbuckler Underground Chemist Rogue, Alchemist VMC

Race Human Two-Weapon Fighting
CL1 Rog/Alc1 Point-Blank Shot, Weapon Finesse; Sneak Attack 1d6
CL2 Rog/Alc2 Chemical Weapons, Combat Training – Quick Draw
CL3 Rog/Alc3 Alchemy, Finesse Training (Dagger); Sneak Attack 2d6
CL4 Rog/Alc4 Debilitating Injury, Scout’s Charge, Precise Splash Weapons
CL5 Rog/Alc5 Precise Shot Rogue’s Edge – Acrobatics, Sneak Attack 3d6
CL6 Rog/Alc6 Weapon Training – Weapon Focus (Dagger)
CL7 Rog/Alc7 Bombs 4d6, Sneak Attack 4d6
CL8 Rog/Alc8 Combat Training – Rapid Shot, Skirmisher
CL9 Rog/Alc9 Improved Two-Weapon Fighting, Bomb 5d6, Sneak Attack 5d6
CL10 Rog/Alc10 Hunter’s Surprise, Rogue’s Edge – Stealth
CL11 Rog/Alc11 Mutagen; Bomb 6d6, Sneak Attack 6d6

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Variant Multiclass Alchemist treats your entire Class Levels as Alchemist for determining your Bombs, under the assumption that you won't get Int to the Bombs; however, Underground Chemist gives you Int to Splash Weapons, along with adding Sneak Attack damage to them, meaning every Bomb is effectively doubled, adding Int to the attack as well.

[CrescentCrux]

As good as that looks, I have one problem:

V, in the movie, doesn't back stab or hit people who are unable to defend themselves. Often it is quite the opposite and he goads them or announces his presence before fighting. As for bombs, he rarely used explosives preferring to use two daggers and overwhelming force or subterfuge, though his character did portray to chemical and explosive knowledge.

Now if your trying for Guy Fox...

[Kalindlara]

He did catch guards and such by surprise in the original comic series. "Dennis never saw it coming."

That said, I feel like the flowing monk archetype needs to be involved here. ^_^

[Eltacolibre]

Rogue + alchemist, already exists tho...the investigator and that's pretty much the whole deal of V.

Technically V is even listed as a master marksman, you could use the Steel Hound archetype as well to grab one or two gunslinger deed/trick. As with weapon finesse and the rapier, you would be using dex anyway.

you already get the alchemical bonuses , which is more than enough to make alchemist fire and whatever alchemical objects that you need.

You can pick up Mutagen as one of your investigator talent, so you can use to enhance your reflexes.

I mean there is nothing wrong with your combo...just that I think might as well use the combo that it is already there.