kinevon
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Yes, firing a pistol, musket, rifle or other gunpowder weapon will provoke an attack of opportunity, the same as using a bow or crossbow. However, loading a gun also provokes.
There is a deed, IIRC, that allows you to use load it without provoking.
There is also the Point Blank Master feat, which would work to let you fire it without provoking.
Nefreet
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The feat you'll want is Deft Shootist.
It allowed my Fighter/Gunslinger to be an effective front line tank.