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So I think I know where I'm going to fall on this question. It's not too huge of a leap.
The Ranged Spellstrike ability allows you to attach a spell that is a ranged touch attack to a ranged attack. Molten Orb does not specify that it is a ranged touch attack, just that it's treated as a splash weapon.
A splash weapon is a ranged touch attack. RSP also specifies that the spell has to be single target, which a splash spell would not be.
Am I looking into it too much? Is it clearly to be allowed?

Amrel |

It would only work as a quickened spell unless the spell you are striking with is a spell that has held charges from a previous round. The limiter that immidiately came to mind is you can only cast one spell per round unless one is quickened.
I believe that is only due to action limits and spells often being standard actions.
Regardless i think the wording is that you hurl the orb as a splash weapon, but it is still a spell, not a ranged weapon attack, as is required by spellstrike.
That being said i wouldn't think this to be game breaking.
Also, someone mentionedoned this working with acid dart, can we get a source for that? If that has been officially cited then i would think that validates this.