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I recommend Inquisitor for infiltration, likely the Infiltrator archetype. They get a good array of skills, some very useful spells, and they're better in 1v1 combat than other characters with infiltration skills (ex: bards, rogues, sorcerers). You also get inflict spells, so you can heal yourself. Since you start at level 5, you'll get Bane right off the bat - it's a great ability. If you aren't going to have melee support you might also consider the Preacher archetype since you do need allies to use Solo Tactics.
For an inquisition, I might recommend the Darkness, Liberation, Travel, or Deception domains. The Darkness domains's level 8 ability isn't quite as nice given you've already got darkvision, but being able to see in magical darkness is still nice, especially if you plan on casting Deeper Darkness. The other three make you harder to pin down.
Consider Nosferatu-born for the Wis bonus.