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Mind fog might work for what you're thinking. It doesn't target Wisdom in the way of ability damage, but it does impose heavy penalties on Wisdom-related rolls.

Resistance |
Does it need to be an actual spell (and if so, does it matter what classes of caster can take it?), or would, for example, the Alchemist's Madness Bombs count?
No, it doesn't. As long as it's a viable way to surprise an enemy and geas them I'm fine. It can't be something prolonged but those bombs seem fine.
Thanks HaraldKlak, it would definitely be something I would need to cast twice (my familiar and myself) to completely disable them
Fatespinner, this is awesome! Once I've got a cohort it will mean unlimited mind slaves.
Azaelas Fayth, I want to perform charms. Nearly all charms have a will save.

Resistance |
This is true... next question what is the primary target you are going after?
I attempted to apply a lesser geas to a cleric and due to their high wisdom score they were able to shrug it off and gag me. I want to be able to use a quickened spell to lower their will and then I want to geas them with 'untie me, tell me the location of the treasure and cut your tongue out'.
But mainly I want to be secure, I need to permanently geas a few fighters, antipaladins and other characters which would be useful on a ship.

Azaelas Fayth |

OK.. the problem you are going to have is they get a will save to negate the penalty...
I'm guessing this is an Evil character as well...
If you have Silent and Still metamagic feats... I personally say kill them then reanimate them as Magus Zombies from Classic Horrors Revisited(?). They get to keep all spellcasting abilities up to a certain point.
If you really don't wanna do that then Mind Fog seems your best option as it stands... though you don't even need to cast it quickened. Though you might need something to get the DC up.

Resistance |
I don't want to kill and reanimate. Anybody who I magically control should be crafting for me. Killing also means that they have to make bluff and disguise checks to make sure that they're alive and I'm sure that in the long term they'll rot as well lest I cast gentle repose on them constantly.
To be honest, I'm thinking touch of idiocy is the best plan. Although it isn't as solid (may roll 2 1's) it is almost certainly more secure due to the complete lack of a save. Even in the worst case scenarios four castings (myself and my familiar, maybe even my cohort and some followers) casting it at the same time will be a perfect way to geas high level, his WIS targets.
I don't think that compulsion is generally a good way to get out of things. It's essentially 'get or good save or you're killed' sort of spell but with charms you can keep talking. Therefore I think I'm going to be using these on high level targets that I've already tied down and such.
EDIT: Ruyan, thanks. 1d3 for 1500gp seems a little overpriced for me. I won't be using it unless it's a really high profile target that I want to enchant.

HaraldKlak |

To be honest, I'm thinking touch of idiocy is the best plan. Although it isn't as solid (may roll 2 1's) it is almost certainly more secure due to the complete lack of a save. Even in the worst case scenarios four castings (myself and my familiar, maybe even my cohort and some followers) casting it at the same time will be a perfect way to geas high level, his WIS targets.
Actually touch of idiocy wouldn't get you that far. Multiple casting of the same spell is not going to stack.
However you could use lesser rod of maximize spell to ensure that -6 penalty on all the mental ability scores.
On top of this, you could use Bestow Curse to give the target a -4 penalty on attack rolls, saves, ability checks, and skill checks. Or bestow curse for a -6 decrease in wisdom.
It might be possible to use both effect from bestow curse, since they are unrelated effects, but I am not sure about it.

Azaelas Fayth |

I OK I wasn't sure it you were planning to keep them for long or not.
Touch of Idiocy only effects them once with the penalty though it might extend the duration... it has been a while since I have need to know anything along those lines.
Touch of Idiocy followed by Bestow Curse and Mind Fog, in what ever order is most effective might work... if the effects stack you could be looking at a near auto-success on the Geas spell.
Though I could be totally wrong. All else fails Grease makes a great spell for a get away. Especially against low reflex saves. ;P slick up the ground and get out of there like your late for a very important date. :3
And yes I am slightly out of it.

Resistance |
I wasn't aware that you were able to apply two seperate metamagics to a spell. I'm also not taking any metamagic feats, I'm only using rods.
Also, bestow curse is a great idea since I can have my familiar cast the touch of idiocy and then I myself can cast bestow curse. If bestow curse will work then I can have one of my followers cast it as well.

Morbios |

But mainly I want to be secure, I need to permanently geas a few fighters, antipaladins and other characters which would be useful on a ship.
Just keep in mind that a geas won't turn them into mind slaves per se (admittedly, you used that term in another post, so could be planning to use other spells)...
The geased creature must follow the given instructions until the geas is completed, no matter how long it takes. [...] A clever recipient can subvert some instructions.
Make sure to keep both considerations of the spell in mind. A ship full of blackguards would doubtless hate your for commanding their servitude in such a way, and could likely communally find at least one loophole in your wording. Just be careful. ;)

Bialaska |
I wasn't aware that you were able to apply two seperate metamagics to a spell. I'm also not taking any metamagic feats, I'm only using rods.
Also, bestow curse is a great idea since I can have my familiar cast the touch of idiocy and then I myself can cast bestow curse. If bestow curse will work then I can have one of my followers cast it as well.
You can only use one metamagic rod on a spell, but if you had the other metamagic feats already, you could apply those. So if you had an Empowered Touch of Idiocy in memory, you could apply the Maximized rod to it for an Empowered Maximized Touch of Idiocy.