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Can a Magus use two-weapon fighting with a throwing weapon and use Spell Combat in the same round? For example, fight with longsword and dagger, meleeing with longsword and throwing the dagger, then use his newly empty hand to use Spell Combat?
I don't think you would be able to.
Two Weapon Fighting takes a full round action, and the Spell Combat description specifies it as a standard action i believe.
Thus, you can't take a Full Round Action and a Standard Action in the same round.