| blahpers |
Attaching a stone to an arrowhead seems like a good way to screw up your shot royally. In any case, the glue needs to be applied and pressed for a round to set. If you shot the arrow and managed to hit the target with the stone, it'd do what any other stone would do--deal some bludgeoning damage and bounce off.
This is assuming that the GM doesn't conclude that the glue would harden after a round of exposure to air anyway; in that event, you'd have very little time to shoot the arrow once the glue was applied. It would be a reasonable conclusion.
Besides, throwing the vial as a called shot to the face seems like it'd be far more effective as a combat trick.