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Equipment: No firearm sized Large or larger is available for purchase. The double hackbut and culverin on Table 3–4 and advanced firearms on Table 3–5 and are not permitted in Pathfinder Society Organized Play. No character may purchase a firearm unless she possesses the Gunsmithing feat and firearms are never considered Always Available; a character must possess enough Fame to purchase any firearm not found on a Chronicle sheet or granted by a class feature. All ammunition except metal cartridges may be purchased.
Ok so as a gunslinger I get the first pistol for free and gunsmithing lets me get a MW for 300gp. Would I be able to upgrade my battered pistol to +1? Or is the "never considered always available" going to prevent me from doing so?
Once it's made MW via the gunsmithing feat, you could upgrade the gun to +1, etc. However, since the firearm is not on the always available list, you would need the fame to cover the total cost of a +1 pistol before you could enchant the item in the first place.