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Bestow Curse can reduce Dex by 6, which will reduce AC by 3.
Any spell or effect that makes a foe Blinded (-2 AC, loses Dex bonus to AC), Cowering (-2 AC, loses Dex bonus to AC), Entangled (-4 Dex = -2 AC), Exhausted (-6 Dex = -3 AC), Fatigued (-2 Dex = -1 AC), Flat-Footed (no Dex to AC), Grappled (-4 Dex = -2 AC), Helpless (+4 bonus to hit, Dex mod is reduced to -5), Paralyzed (Dex 0 = -5 AC), Pinned (-4 AC, loses Dex bonus to AC), Prone (-4 AC vs. melee attacks, +4 AC vs. ranged attacks) or Stunned (-2 AC, loses Dex bonus to AC) can help, such as grease or color spray or blindness or various summon monster spells (constrictor snakes and giant spiders and wolves can grapple, entangle or render foes prone, and centipedes can damage Dex with their poison, although few foes will fail that save DC...).
Mundane options, like a tanglefoot bag, net, whip, etc. can also help.
Making an ally Invisible (+2 attack rolls, ignores Dex bonus of foe) or Sundering armor worn by the monster (half AC bonus, round down) can also help.