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Well, specifically, unarmed strike + eidolon's rake.
This would also apply to any creature that managed to get weapon attacks +pounce with a rake. (beastmorph Alch or some such)
Would the rake attacks suffer the standard -5 for mixing natural attacks?
(specifically, a Synthesist's Rake would happen every successful Grab check with an unarmed strike)
If there's weapon attacks and natural attacks in the same round, apply the penalty.