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Hello, Can a character use a weapon or wear an armor enhanced with a potency rune that is superior to his proficiency in armon or weapons?

For example, is a 20th level paladin able to use a +5 weapon if his weapon proficiency is only master and not legendary?

If not, are there ways to upgrade a proficiency?

Thanks

Can I use PaO to duplicate a level 8 spell with the possibility of a permanency effect (such as giant form 2 dragon form 3) or can i exceed the effect of greater polymorph (such as Giant form 1)? By RAW id say yes, but objectively it would be far stronger than other spells of the same level, maybe better than a 9° level spell.

What do you think about?

In another topic is being explained that Persistent spell is more usefull than Heighten spell in most of cases.
Here i'd like to know if the same spell is capable to substitute even Empower spell other than Heighten spell in a sorcerer feats list.

The 100% of the damage is better than the 150%\2? Math said yes, but isn't so simple, what's your thought?