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I did an Unchained Rogue: Makeshift Scrapper / Alchemist Vivisectionist / Moonshiner combo that gets sap master working by 5th lvl against anyone who can be bluffed. Not PFS legal, uses 3rd party rules.
This is for a Drow campaign, so I'm a drow; also would work well for a Halfling. Racial abilities, I swapped in the bonus to bluff check and stealth. Traits, I took Surprise Weapon (+2 to hit with improvised weapons) and Nonchalant Thuggery (+4 bluff)
For gear, I took an everfull Umbrite tankard. And "standard" rogue gear (buckler, mithral CS, etc)
Lvl 1: UR1: get catch off guard, throw anything, bludgeoner.
Lvl 2: UR2: take combat trick: Improved Catch off guard. Now you can sneak anyone who can be bluffed.
Lvl3: Al1: Moonshine stupor gives us great stat bonuses every fight. Feat: sap adept.
Lvl4: UR3: Finesse Training (Tankard)
Lvl5: UR4: fast getaway and sap master (at this point, 6d6 +6 + 1d4 + dex bonus; add 2d6 +2 if you enchant your improvised weapon with "ambush")

If I've made any mistakes or you have improvements, let me know.

I did an Unchained Rogue: Makeshift Scrapper / Alchemist Vivisectionist / Moonshiner combo that gets sap master working by 5th lvl against anyone who can be bluffed. Not PFS legal, uses 3rd party rules.
This is for a Drow campaign, so I'm a drow; also would work well for a Halfling. Racial abilities, I swapped in the bonus to bluff check and stealth. Traits, I took Surprise Weapon (+2 to hit with improvised weapons) and Nonchalant Thuggery (+4 bluff)
For gear, I took an everfull Umbrite tankard. And "standard" rogue gear (buckler, mithral CS, etc)
Lvl 1: UR1: get catch off guard, throw anything, bludgeoner.
Lvl 2: UR2: take combat trick: Improved Catch off guard. Now you can sneak anyone who can be bluffed.
Lvl3: Al1: Moonshine stupor gives us great stat bonuses every fight. Feat: sap adept.
Lvl4: UR3: Finesse Training (Tankard)
Lvl5: UR4: fast getaway and sap master (at this point, 6d6 +6 + 1d4 + dex bonus; add 2d6 +2 if you enchant your improvised weapon with "ambush")

If I've made any mistakes or you have improvements, let me know.

I did an Unchained Rogue: Makeshift Scrapper / Alchemist Vivisectionist / Moonshiner combo that gets sap master working by 5th lvl against anyone who can be bluffed. Not PFS legal, uses 3rd party rules.
This is for a Drow campaign, so I'm a drow; also would work well for a Halfling. Racial abilities, I swapped in the bonus to bluff check and stealth. Traits, I took Surprise Weapon (+2 to hit with improvised weapons) and Nonchalant Thuggery (+4 bluff)
For gear, I took an everfull Umbrite tankard. And "standard" rogue gear (buckler, mithral CS, etc)
Lvl 1: UR1: get catch off guard, throw anything, bludgeoner.
Lvl 2: UR2: take combat trick: Improved Catch off guard. Now you can sneak anyone who can be bluffed.
Lvl3: Al1: Moonshine stupor gives us great stat bonuses every fight. Feat: sap adept.
Lvl4: UR3: Finesse Training (Tankard)
Lvl5: UR4: fast getaway and sap master (at this point, 6d6 +6 + 1d4 + dex bonus; add 2d6 +2 if you enchant your improvised weapon with "ambush")

If I've made any mistakes or you have improvements, let me know.

Has anyone thought of taking 2 levels of Soul Eater for the Level Drain ability, and a Conductive weapon? Combine this with Soul Pool's "recover spell slot" ability, and you get a level 1 spell back for each negative level you drain (2 on a crit), so unlimited shocking grasp at level 7.