Read the little instruction booklet that came with the deck.
The position of the icon that tells you what stat the card matches determines what the alignment is.
Hi, i have the Harrow deck cards, how can i tell what card matches what alignment?? i cant see any indication on the cards as to what alignment it corresponds too... might be being thick..
The alignment positions go like such: the top row is Good, the middle row Neutral, and the bottom row is Evil. The left column Lawful, middle column is neutral, and the right column is Chaotic. The logic is pretty easy to catch once you look at both the title of the card, the art and the position of the symbol (as well as what the symbol is).
I've had a lot of fun with the deck so far. My players in CotCT are a bit paranoid to use it.