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I made a cloud of holy mist spell here, but the holy rainstorm is also a fairly common theme. I'm pretty sure I saw something to that effect in 2nd edition (based off of the Cloudburst spell that showed up in the original Unearthed Arcana, IIRC), but I don't recall seeing it again in 3rd edition.
Edit: Just looked up Anarchic Storm, and yeah, that's pretty much the stuff, although it's level 3, does more damage than normal holy water, and randomly hits something in it's area with a lightning bolt each round, so it's definitely more powerful than a bog-standard 'rain of holy water' spell!