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Long time reader, first time poster. Sorry if there's any errors in format!
1. The Ragechemist Alchemist: I absolutely love this in concept, and if Prestige Classes are going the way of the dinosaur, the reintroduction of this Amazing Bulk would be a good way to borrow things from the Master Chemyst too! Alchemist's are already monstrously versatile, but this lets them retain a fair measure of that versatility while allowing them to be even more of a melee monster. The Will save penalty is nice and thematic, though I suppose I do wish the STR bonus given by the archetype scaled a little bit higher than just +2.
2. The Tower Shield Specialist Fighter: I'm a big fan of playing turtle-type character, and while tower shields might not be 100% optimal for everyone, this archetype makes them pretty particularly meaty, and I've had a blast with it in the past. It felt like playing a brick wall, which, given the squishy nature of the rest of my party at the time, was both enjoyable and fairly useful.
3. The Witchguard Ranger: I first played this archetype when a buddy of mine was playing a Sorcerer or something, and it's what lead me to love the Bodyguard/In Harm's Way feats. Also, being able to retain some relevance as a martial in a world of casters was nifty. I played him a little bit like a Mafioso-type bodyguard, it was fun.
4. The Underground Chemist: I know that The Alchemist is already a core class, so borrowing class features from something from the same book might be a bit silly, but boy howdy did I love the character I made using this archetype. It gives things like Alchemist's Fire usefulness all the way to the endgame, it lets a Rogue potentially have all sorts of useful things up their sleeves (aside from seeking traps and waiting to plunk away sneak attacks), and in terms of flavor? It's nothing but wonderful. One of my favorite single archetypes I've ever come upon.
5. The Archaeologist Bard: I'm pretty sure I've seen this mentioned a few times here already, so I won't add anything more, except: I really enjoy this archetype, it's fun and flavorful without being mechanically overpowered or complicated.