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1. Promethean Alchemist and Vivisectionist - As a standard alchemist your character is already perfectly flavored as one of the most famous doctors in fiction, Henry Jekyll. These two archetypes give you the opportunity to play as two others; namely, Dr. Frankenstein and Dr. Moreau.
2. Brazen Deceiver Bard - If I wanted to play in a campaign as a Han Solo type scoundrel, this is the archetype I would choose.
3. Forgemaster Cleric - Though I feel like using INT is tough on the cleric, I love the idea of using runic casting.
4. Trapper Ranger - Not all rangers are magical. I like that the ranger gains mechanical utility in place of its spellcasting with this class archetype.
5. Zen Archer Monk - My favorite archer build. Not much else to say.