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G'day Eris,
All characters in PFS start at level 1 and level up after playing several scenarios (depending on if you are playing normal or slow experience track).
As to what you can play, first have a read of the Guide to Organised Play (found here) which gives you the specific character creation process, as well as the other PFS specific rules (such as limitations on crafting and so on)
After that, head over to the additional resources document, which details which publications and what rules/feats/items and so on are legal for play in the organised play campaign.
Above all, have fun, welcome to the Pathfinder Society, if you have any other questions feel free to ask