As I'm currently playing the 3.5e prestige class Fiend of Corruption, this topic has been discussed at great length in our group. The conclusions we've reached are
1. I may not deliberately injure, inflict disease or torture the subject into signing my proffered contract, not use other party members to do the same.
2. I may not use Dominate Person, Command, Geas or other mind affecting spells/sla to get a signature, with the exception of Charm Person.
3. I can withdraw my favor (+3 to an attribute, -6 if i withdraw it) and use the stat penalty to encourage the subject.
4. I can bribe, lie and blackmail mortals into committing progressively more evil acts until signing is the only way out for them.
5. I can lie about the details of the contract as much as i want. If they can't read an 18 page document in Infernal, and pass several opposed profession: Barrister checks, too bad.
That being said, I'm mostly focusing on one other PC, by offering various bonuses (wings, reach etc) in exchange for her committing increasingly evil acts until the offer of the half-fiend template and/or immortality in exchange for her soul seems reasonable.
Oh, and I'm currently the only Evil PC in the group, and despite that I've made no secret of the fact I'm playing an Imp, all bar one party member trusts me.