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My critical-specalist fighter uses a Silversheen Nodachi. Admittedly I haven't needed either the silver or the rust-proof features of the Silversheen yet, but there also hasn't been a real occasion to use the power of adamantine either.
I do think Cold Iron has come up, but I didn't want the rather sizable cost increase.
And don't forget the new materials from Ultimate Equipment. Elysian Bronze gives you +1 damage against two large categories of creatures (Magical Beasts and Monstrous Humanoids). And after you hit a valid target you get a +1 to that specific creature until you hit another valid target.