Bleed is too slow for normal combat use. It's perfect for guerrilla fighting but adventurers in PF rarely fight like that. Hamstring strike would be better at lower levels but it's an advanced talent - and you probably get double debilitation first. Slow reactions is reliably useful though fairly minor.
Offensive defense is for the original (not unchained) rogue only.
Eerie disappearance looks fun and useful.
Surprise attack may be useful, but there's a pretty good chance that either you'll win initiative (high dex) or that the enemy fails to spot you (high stealth) or that you're simply not in a surprise situation. If you often have a bunch of unstealthy people trying to sneak along with you it's better. Even then snap shot may be better.
Underhanded is pretty hard to use. You need to draw and use a concealed weapon during the surprise round. The action economy makes this difficult for most.
Fast getaway just doesn't seem that useful.
On other relevant talents - dampen presence is how to not be seen by enemies with blindsight/sense. You'll want it as a talent or feat eventually. Umbral gear is fun but possibly not that useful. If your GM uses area effects a lot then without a trace ay be useful.
Rogues usually use their talents to get more feats (e.g. combat trick, weapon training) rather than spending feats to get more talents.
Check in a hard copy of the core rulebook, or on archives of Nethys - hamstring strike is an advanced rogue talent. For that matter I just looked on d20pfsrd and I see hamstring strike listed under advanced talents. I don't know where you're getting that it's not an advanced talent.
If he were to acquire a ki pool of the ninja variety for the extra attack at full BaB, that could prove helpful.
Upon further research unchained rogues cannot get access to a ki pool.
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Bleeding Srike probably isn't worth taking unless you are running into a lot of Damage Resistant enemies. That said, I have a non-lethal rogue build that rolls double SA dice. So an extra 8-10 damage per round is pretty good. I didn't end up taking it however, as I do so much damage, that I 1 shot most enemies and 2-3 hits kills most bosses.
Offensive Defense is great, especially against the big bad.
My Rogue/Barbarian had Surprise Attack. It works ok, but I didn't get that much use out of it. I would choose the Rogue Scout Archetype and get Scouts Charge at level 4 and Skirmisher at level 8. Makes Surprise Attack somewhat worthless.
Eerie Disappearance looks pretty awesome. I haven't seen that before.
Hamstring Strike looks useful, but you are giving up guaranteed damage for something that will only work occasionally. Personally, I wouldn't give up my damage dealing for any of the * abilities. Especially when Debilitating Injury is at 4th level.
The unchained rogue gets a subset of the chained rogue's talents. Originally that was
Rogue Talents: Assault leader, black market connections, canny observer, cunning trigger, deft palm, distracting attack*, fast getaway, firearm training, getaway artist, grit, iron guts, ninja trick, positioning attack, quick disguise, quick trapsmith, rope master, strong impression, strong stroke, survivalist, swift poison, underhanded, wall scramble.
Advanced Rogue Talents: Another day, confounding blades*, deadly cocktail, familiar, fast tumble, frugal trapsmith, getaway master, hide in plain sight, hunter’s surprise, knock-out blow, redirect attack, rumormonger, stealthy sniper, unwitting ally, weapon snatcher.
A bunch of sources since have added their new talents but you'll see offensive defense isn't there (nor is hamstring strike, I missed that before) and both existed at the time the unchained rogue came out. I think debilitating strike was meant to replace it - I can't remember if some developer said that or if it was just interpreted from the new feature and offensive defense's absence.
Weapon snatcher (ultimate combat) isn't on the list either Atalius. Edit: oops, it is. Didn't realise it was an advanced talent.
May I suggest another * marked talent?
Emboldening Strike from Blood of Shadows - basically Offensive Defense at half value, but on Saving Throws (so, exactly what mister "worst base saves a PC class can have" needs). And, like Offensive Defense, it even stacks with itself!
Does debilitating strike stack with the sneak attack talents (like bleed, slow, etc.)? I know the talents can’t stack with each other.
Read the description: "At 4th level, whenever a rogue deals sneak attack damage to a foe, she can also debilitate the target of her attack, causing it to take a penalty for 1 round (this is in addition to any penalty caused by a rogue talent or other special ability)." Emphasis mine.