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Spell Focus Necromancy or Enchantment or both.
Extra Hex for early levels, does depend on your game or retraining.
Accursed Hex if you like Evil Eye and Ice Tomb.
A lot of Wizard stuff applies - Spell Penetration is a given, Quicken almost certainly, Craft Wondorus Items if that applies to your game.
Ley Line Guardian probably wants Great Fortitude or at least a good Con score because of all the Fort saves you have to make with the archetype.
You may have room for a fun one, Deific Obedience gives you a lot of entertainment bang for your buck if playing to high level.
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Guides. Just scroll down to witches section. Would focus on things that improved debuffing. Particularly Enervation and Evil eye
If your GM allows it, Ability Focus: Slumber Hex is the definition of broken.
extra hex times a lot, accursed hex, improved initiative, quicken spell, craft wondrous item
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Improved Initiative, Toughness, and Combat Casting are always good for all-rounders, especially since the witch, lacking spells like Mirror Image, is one of the squishiest casters out there. Complement with useful metamagics - Persistent Spell, Silent Spell, and Quicken Spell are some of my faves.
For the debuff witch, Spell Focus: Necromancy or your preferred school is good.
For the rare summon-focused witch, you'll want Spell Focus: Conjuration, Augmented Summoning, Superior Summoning, and Evolved Summons, though for a Leyline witch this is probably a poor choice. Improved Familiar would also be fantastic if you weren't trading it out.