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What skill is relevant for knowing that this phiol of water is Alchemist fire or liguid ice?
What are the DCs?
I don't think there is one; in the magical world of Pathfinder, everything is properly labelled.
Well, if they're common items, it should be a DC 10 Craft (alchemy) check, shouldn't it?
Any creature that has a need to drink can tell the liquid isn't water. Craft (alchemy) identifies it. I might set the DC equal to the craft DC - 10. Craft skills can be used untrained.