Arazyr |
There is Defensive Combat Training, but that's for CMD. I don't know of an equivalent for CMB off hand, but it would be easy to houserule one in. Ask your GM.
On the other hand, things like Improved Bull Rush (and equivalents for other combat maneuvers) would also help, if you have specific maneuvers in mind. (Though you may have already thought of those.)
Ikonoclast |
If this is just for you animal companion (horse) then an amulet of mighty fists as previously suggested, with just a base +, should apply to all of the horses natural attacks. It can be assumed that most of it's combat maneuvers would use it's bite or hooves to some extent, and therefore should be able to apply the bonus. There may be some exceptions, but that'll be up to you and your DM to interpret.