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Are there any books where unique spells are granted to spellcasters from their god outside of inner sea gods?
Deity articles in APs. Geryon has one.
Mephistopheles in Pathfinder #102: Breaking the Bones of Hell
Yeah, Mahathallah has one in AP #99, the Create Drug spell.
Actually very few, but a wonderful new room to build onto the house.
Archives of Nethys lists them and their source under each deity's page.