With the Exalted PRC from Inner Sea Gods it states for Expanded Portfolio:
At 5th level, the exalted further increases her already impressive knowledge of her chosen deity's faith and is rewarded with increased powers in one of the spheres over which her deity holds sway. The exalted chooses a domain of her chosen deity to which she gains access, using her exalted level as her effective cleric level.
The exalted can also can use each of the chosen domain's spells once per day as a spell-like ability, with a caster level equal to her exalted level. The exalted can use each spell-like ability only if she is able to cast divine spells of that level. If the exalted has any domain spell slots, she is also able to cast the chosen domain's spells in those slots as normal.
I understand that the ability to cast domain spells as SLA 1/day scales off the Exalted level but I'm guessing that does not apply if they are cast from normal domain slots (ie they are cast as per spellcasting level)- hence the phrase as normal? Leading on from this, if that is the case, I assume the same would apply if a cleric was scribing the domain spell to a scroll?
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Yes, "as normal" means based on the spellcasting ability of the class that offers the domain slots - which likely will be advanced by the exalted PRC. So a cleric 5 / exalted 5 can cast domain spells from any of their 3 domains as if they were a 10th level cleric, in addition to having the 1st, 2nd, and 3rd level spells from one domain as SLA 1/day (as a 5th level caster). The cleric's domain powers however would function as a 5th level cleric.