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John Cena isn't terribly Chaotic; he's generally in favor of fair play and supports legitimate authority. He hasn't turned heel in over a decade, and despite being taunted by the crowd with "John Cena Sucks" chants, he remains positive, accepting that not everyone will support him, and the fans have a right to cheer whoever they want. He's a hero to children, has done more Make a Wish visits than any celebrity every (no, really), and is out in front of any charity stuff WWE gets involved with. He can be pushed into bending the rules, but I'd say he's more of a Neutral Good deity, and I could see justifying Lawful Good if only so that he could support an order of Paladins (which seems just about perfect for him).
As for domains, I'd say Strength, Community, and Nobility match up with his "Hustle, Loyalty, Respect" mantra, and I'd add in Good to round it all out. His followers will already have access to the subdomains of each, so they can take the Fist subdomain if you like.