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As a big fan of Joan of Arc and Paksenarrion, if transported to Golarion I would definitely become a devotee of Iomedae. The problem is that I am really not at committed to being Lawful as I would like, so I'd probably not be a very strict adherent but I love her ideals. Also, as a cultural Catholic I think her tradition would seem more homelike.
IRL, I am an ordained Buddhist priest, but I find Irori annoying. His tradition kind of stands in for the Shao Lin types, but he is no Buddha. He just seems like a stern taskmaster and who wants to end up on Axis - a realm of cold impersonal Law? Brr... Unlike the Buddha (Teacher of Gods and Men), Irori is a mere god and isn't even committed to Good. I could deal with the Empyreal Lord Korada however. He is cool, and has more of the bodhisattva vibe.
I do like Pharasma - she seems civilized, and though not benevolent, she dutifully ensures that the cycle of birth and death operates smoothly and fairly for everyone.
I confess to having a gruesome and morbid fascination with poetic justice and creative forms of damnation such as one finds in Dante's Inferno (have read the Divine Comedy twice in two different translations) and I like the idea of the Machiavellian schemer who nevertheless abides by a code of honor (granted a bit twisted) and so while I would never have anything to do with Asmodeus, I find him fascinating. He is truly the cosmic Magnificent Bastard (as per tvtropes) of Golarion's cosmology.
Calistria truly annoys me. She just seems selfish and mean-spirited. Who needs that kind of drama?
Erastil is too conservative, rural, and patriarchal for my tastes.
Shelyn is the goddess of things I deeply appreciate and admire.
Abadar also annoys me. He just seems like the god of capitalism, imperialism, and colonialism - all things I don't much approve of. Is there a Golarion god for the proletariat?
As a bartender I should really be a worshipper of Cayden, and I do appreciate having good drinking buddies. On the other hand, drunks annoy me (unless they are tipping me well), and too many of my drinking buddies lately have been mooches and/or ugly drunks. I also get kind of a frat boy vibe from Cayden (granted, he is at least a good natured lug). So I wouldn't have much to do with him either.
In general I would approve of all other Good deities.
The Neutral deities and esp. Chaotic Neutral deities I would actively dislike as they are at best impersonal and callous and at worst violent and destructive).
The Evil deities aside from Asmodeus would be worthy of nothing but my contempt and I would kill their adherents as fast as I could identify them (or at least report them to Lawful authorities to deal with).