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I am doing a similar thing in a campaign that I am soon to start. One of the civilized nations is strictly monotheistic, and they differentiated by their orders. Much like Franciscans, Jesuits, Dominicans, and the other Catholic orders venerate and follow the examples of specific saints and holy figures, these orders follow the narrow teachings and examples of old high priests, heroes, and martyrs.
One thing I am doing to differentiate the cleric a bit (particularly within this religion) is to give all caster spontaneous domain spells and take away spontaneous cures. This means that those that follow a healing order are particularly respected, and no one asks the crusaders to patch up their scrapes.